The Effect of Temperature on the Rate of Reactions NEET Questions

The Effect of Temperature on the Rate of Reactions MCQ Questions

13.
If the activation energy of a reaction is 100 kJ mol⁻¹, the presence of a catalyst lowers it by 75 kJ mol⁻¹. The rate of the reaction at 27 °C will increase by a factor of (R = 8.314 J K⁻¹ mol⁻¹):
A.
≈ 10²
B.
≈ 10¹³
C.
≈ 10²⁰
D.
≈ 10⁵
ANSWER :
B. ≈ 10¹³
14.
For a reaction, the rate constant at 500 K is twice the rate constant at 400 K. The activation energy (in kJ mol⁻¹) is approximately (R = 8.314 J K⁻¹ mol⁻¹):
A.
11.5
B.
23.0
C.
5.76
D.
57.5
ANSWER :
A. 11.5
15.
The rate constant of a reaction at 500 K is 1.6 × 10³ times the rate constant at 400 K. The activation energy of the reaction is (log 1600 ≈ 3.204, R = 8.314 J K⁻¹ mol⁻¹):
A.
≈ 61 kJ mol⁻¹
B.
≈ 22 kJ mol⁻¹
C.
≈ 244 kJ mol⁻¹
D.
≈ 122 kJ mol⁻¹
ANSWER :
D. ≈ 122 kJ mol⁻¹
16.
The activation energy of a reaction can be determined experimentally from the slope of the plot:
A.
ln k versus 1/T
B.
1/k versus T
C.
ln k versus T
D.
k versus T
ANSWER :
A. ln k versus 1/T
17.
The minimum energy that the colliding molecules must possess in order to react is called:
A.
internal energy
B.
threshold energy
C.
activation energy
D.
free energy of reaction
ANSWER :
B. threshold energy
18.
Activation energy of a reaction is best represented by:
A.
Ea = Average energy of products – Average energy of reactants
B.
Ea = Threshold energy + Average energy of reactants
C.
Ea = Energy of products – Threshold energy
D.
Ea = Threshold energy – Average energy of reactants
ANSWER :
D. Ea = Threshold energy – Average energy of reactants