The Effect of Temperature on the Rate of Reactions NEET Questions

The Effect of Temperature on the Rate of Reactions

The Effect of Temperature on the Rate of Reactions MCQ Questions

13.
If the activation energy of a reaction is 100 kJ mol⁻¹, the presence of a catalyst lowers it by 75 kJ mol⁻¹. The rate of the reaction at 27 °C will increase by a factor of (R = 8.314 J K⁻¹ mol⁻¹):
A.
≈ 10²
B.
≈ 10¹³
C.
≈ 10²⁰
D.
≈ 10⁵
ANSWER :
B. ≈ 10¹³
14.
For a reaction, the rate constant at 500 K is twice the rate constant at 400 K. The activation energy (in kJ mol⁻¹) is approximately (R = 8.314 J K⁻¹ mol⁻¹):
A.
11.5
B.
23.0
C.
5.76
D.
57.5
ANSWER :
A. 11.5
15.
The rate constant of a reaction at 500 K is 1.6 × 10³ times the rate constant at 400 K. The activation energy of the reaction is (log 1600 ≈ 3.204, R = 8.314 J K⁻¹ mol⁻¹):
A.
≈ 61 kJ mol⁻¹
B.
≈ 22 kJ mol⁻¹
C.
≈ 244 kJ mol⁻¹
D.
≈ 122 kJ mol⁻¹
ANSWER :
D. ≈ 122 kJ mol⁻¹
16.
The activation energy of a reaction can be determined experimentally from the slope of the plot:
A.
ln k versus 1/T
B.
1/k versus T
C.
ln k versus T
D.
k versus T
ANSWER :
A. ln k versus 1/T
17.
The minimum energy that the colliding molecules must possess in order to react is called:
A.
internal energy
B.
threshold energy
C.
activation energy
D.
free energy of reaction
ANSWER :
B. threshold energy
18.
Activation energy of a reaction is best represented by:
A.
Ea = Average energy of products – Average energy of reactants
B.
Ea = Threshold energy + Average energy of reactants
C.
Ea = Energy of products – Threshold energy
D.
Ea = Threshold energy – Average energy of reactants
ANSWER :
D. Ea = Threshold energy – Average energy of reactants