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Kohlrausch’s Law and its Applications NEET Questions
NEET SYLLABUS
Physical Chemistry - Redox Reactions and Electrochemistry
Electronic Concepts of Oxidation and Reduction
Redox Reactions
Oxidation Number, Rules for Assigning Oxidation Number
Balancing of Redox Reactions
Electrolytic and Metallic Conduction
Conductance in Electrolytic Solutions
Molar Conductivities and their Variation with Concentration
Kohlrausch’s Law and its Applications
Electrochemical Cells (Electrolytic and Galvanic Cells, Different Types of Electrodes,...)
Nernst Equation and its Applications
Fuel Cells
Dry Cell and Lead Accumulator
Relationship between Cell Potential and Gibbs Energy Change
Kohlrausch’s Law and its Applications MCQ Questions
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1.
Kohlrausch's law of independent migration of ions states that:
A.
At infinite dilution, each ion makes a definite contribution to the molar conductivity of an electrolyte irrespective of the nature of the other ion
B.
All electrolytes are completely dissociated at any dilution
C.
Molar conductivity of an electrolyte is independent of temperature
D.
Conductivity of a solution always increases with concentration
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ANSWER
:
A. At infinite dilution, each ion makes a definite contribution to the molar conductivity of an electrolyte irrespective of the nature of the other ion
2.
The mathematical form of Kohlrausch's law for an electrolyte is:
A.
Λm° = ν₊λ°₊ × ν₋λ°₋
B.
Λm° = (λ°₊ × λ°₋) / 2
C.
Λm° = ν₊λ°₊ − ν₋λ°₋
D.
Λm° = ν₊λ°₊ + ν₋λ°₋
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ANSWER
:
D. Λm° = ν₊λ°₊ + ν₋λ°₋
3.
In the equation Λm° = ν₊λ°₊ + ν₋λ°₋, the symbol λ° represents:
A.
Equivalent conductivity at unit concentration
B.
Specific conductance at 1 M
C.
Conductivity of pure water
D.
Limiting ionic conductivity (ionic conductivity at infinite dilution)
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ANSWER
:
D. Limiting ionic conductivity (ionic conductivity at infinite dilution)
4.
Kohlrausch's law is strictly valid only at:
A.
Infinite dilution
B.
Standard concentration of 1 M
C.
Saturation concentration
D.
All concentrations equally
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ANSWER
:
A. Infinite dilution
5.
Kohlrausch's law is also called the law of:
A.
Independent migration of ions
B.
Constant proportions
C.
Equipartition of conductivity
D.
Mass action
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ANSWER
:
A. Independent migration of ions
6.
For NaCl, the limiting molar conductivity is given by:
A.
Λm°(NaCl) = λ°(Na⁺) + λ°(Cl⁻)
B.
Λm°(NaCl) = ½[λ°(Na⁺) + λ°(Cl⁻)]
C.
Λm°(NaCl) = λ°(Na⁺) − λ°(Cl⁻)
D.
Λm°(NaCl) = λ°(Na⁺) × λ°(Cl⁻)
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View Answer
Rough Work
Error
ANSWER
:
A. Λm°(NaCl) = λ°(Na⁺) + λ°(Cl⁻)
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