Halogens, Oxygen, Nitrogen, and Sulphur NEET Questions

Halogens, Oxygen, Nitrogen, and Sulphur MCQ Questions

13.
In the nitrogen detection test, the sodium cyanide (NaCN) present in the fusion extract first reacts with ferrous sulphate to form which intermediate compound?
A.
Ferric hydroxide directly
B.
Iron(III) chloride
C.
Sodium ferrite
D.
Sodium hexacyanoferrate(II) [Na₄Fe(CN)₆]
ANSWER :
D. Sodium hexacyanoferrate(II) [Na₄Fe(CN)₆]
14.
In Lassaigne's test, one common method for detecting the presence of sulphur involves treating the sodium fusion extract with freshly prepared sodium nitroprusside solution, which gives a characteristic:
A.
Bright yellow precipitate
B.
Violet (or deep purple) colouration
C.
Prussian blue colouration
D.
Bright orange colouration
ANSWER :
B. Violet (or deep purple) colouration
15.
The violet colouration observed in the sodium nitroprusside test for sulphur is due to the formation of which compound?
A.
Ferric sulphide
B.
Lead sulphide
C.
Sodium thionitroprusside (a sulphur-nitroprusside complex)
D.
Prussian blue
ANSWER :
C. Sodium thionitroprusside (a sulphur-nitroprusside complex)
16.
An alternative test for detecting sulphur in the sodium fusion extract involves treating it with lead acetate solution after acidifying it with acetic acid, which gives a characteristic:
A.
Black precipitate (of lead sulphide)
B.
Bright yellow solution
C.
White precipitate
D.
Blue precipitate
ANSWER :
A. Black precipitate (of lead sulphide)
17.
The chemical formula of the black precipitate formed in the lead acetate test for sulphur is:
A.
PbCO₃ (lead carbonate)
B.
PbSO₄ (lead sulphate)
C.
PbS (lead sulphide)
D.
PbCl₂ (lead chloride)
ANSWER :
C. PbS (lead sulphide)
18.
In Lassaigne's test, the presence of halogens in the sodium fusion extract is detected by acidifying the extract with dilute nitric acid and then adding:
A.
Silver nitrate solution
B.
Ferrous sulphate solution
C.
Sodium nitroprusside solution
D.
Lead acetate solution
ANSWER :
A. Silver nitrate solution