B. The reverse process — a part of the vessel getting cooler spontaneously while the base warms — violates the Second Law (Clausius statement)
14.
An explosive chemical reaction (e.g., petrol vapour and air ignited by a spark) is irreversible because:
A.
The spark cannot be re-applied
B.
The reaction is too slow
C.
The reaction takes the system to highly non-equilibrium states; pressure and temperature are not uniform — and the products cannot spontaneously reassemble into reactants
C. The reaction takes the system to highly non-equilibrium states; pressure and temperature are not uniform — and the products cannot spontaneously reassemble into reactants
15.
Gas diffusing from a cylinder to fill an entire room is listed in NCERT as an example of an irreversible process. The process cannot spontaneously reverse because:
A.
The reverse (all gas spontaneously returning to the cylinder) has an astronomically low probability — it would also violate the Second Law
D. In a non-quasi-static process, the system passes through non-equilibrium states where P and T are not well-defined, making exact reversal impossible
18.
In a quasi-static process, the condition imposed on pressure is:
A.
Pressure is always maximum
B.
Pressure is always zero
C.
At every stage, the difference between the system's pressure and external pressure is infinitesimally small